Low-power devices requirements
Two types of low-power wireless devices are being utilized in IIoT applications. The vast majority of devices draw micro-amps of current and are mainly powered by industrial grade primary (non-rechargeable) lithium batteries. In addition, there are a growing number of applications that draw milli-amps of current, enough to prematurely exhaust a primary battery, typically requiring the use of an energy harvesting device in combination with an industrial grade rechargeable Lithium-ion (Li-ion) cell to store the harvested energy.
Virtually all leading brands of MTUs are powered by bobbin-type lithium thionyl chloride (LiSOCl2) chemistry, which is the preferred choice among primary (non-rechargeable) batteries.
Bobbin-type LiSOCl2 chemistry offers unique performance characteristics, including the highest capacity and energy density of any commercially available chemistry. These cells also feature the widest temperature range (-80°C to 125°C) along with the lowest annual self-discharge rate of any competing chemistry. Achieving a lower self-discharge rate translates into a lower total cost of ownership, which is especially valuable for applications involving remote locations and extreme environments.
Minimizing battery self-discharge
All batteries experience some amount of annual self-discharge, even when disconnected from an external load. Bobbin-type LiSOCl2 cells feature the lowest self-discharge rate of all, mainly by harnessing the passivation effect.
Passivation occurs when a thin film of lithium chloride (LiCl) forms on the surface of the lithium anode, thus impeding the chemical reactions that cause battery self-discharge. Whenever a load is placed on the cell, this passivation layer causes high initial resistance along with a temporary drop in voltage until the passivation layer starts to dissipate—a process that keeps repeating whenever the load is removed.
Cell passivation is also influenced by other factors, including: cell capacity; length of storage; storage temperature; and discharge temperature. Partially discharging a cell then removing the load increases the passivation effect relative to a new battery. While high levels of passivation can be beneficial to extending battery life, too much of it can be problematic if it blocks energy flow.
A battery’s self-discharge rate is further influenced by the purity of raw materials and the method by which the cell is manufactured. A superior quality bobbin-type LiSOCl2 cell loses just 0.7% of its total capacity each year due to self-discharge, enabling up to a 40-year battery life. By contrast, an inferior quality bobbin-type LiSOCl2 cell can lose up to 3% of its nominal capacity annually due to self-discharge, exhausting 30% of its nominal capacity every 10 years, reducing battery operating life to as little as 10-15 years.
The potential for 40-year battery life was validated by Aclara (formerly Hexagram), a supplier of smart infrastructure technologies to gas, water, and electric utilities. When replacing its older MTUs with newer generation technology, Aclara tested random samples of the original batteries and found that they had retained a significant amount of unused capacity even after 28+ years in the field.